The effect of pressure on the equilibrium in the Diels-Alder reaction between 9-chloroanthracene and tetracyanoethylene

被引：0

作者：

Kiselev, VD ^{[1
]}

Kashaeva, EA ^{[1
]}

Konovalov, AI ^{[1
]}

机构：

[1] Kazan State Univ, AM Butlerov Chem Res Inst, Kazan 420008, Russia

来源：

MENDELEEV COMMUNICATIONS | 1998年 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Equilibrium constants for the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene have been determined in the pressure range 0-970 kg cm(-2) in 12-dichloroethane at 298 K and the value of the reaction volume (-20.6+/-1.5 cm(3) mol(-1)) has been compared with the difference in partial molar volume of the dienophile (107.8+/-0.2), diene (170.7+/-0.5) and adduct (255.5+/-1.5 cm(3) mol(-1)).

引用

页码：192 / 193

页数：2

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