The effect of pressure on the equilibrium in the Diels-Alder reaction between 9-chloroanthracene and tetracyanoethylene

被引：0
|
作者：
Kiselev, VD [1 ]
Kashaeva, EA [1 ]
Konovalov, AI [1 ]
机构：
[1] Kazan State Univ, AM Butlerov Chem Res Inst, Kazan 420008, Russia
来源：
MENDELEEV COMMUNICATIONS | 1998年 / 05期
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D O I：
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Equilibrium constants for the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene have been determined in the pressure range 0-970 kg cm(-2) in 12-dichloroethane at 298 K and the value of the reaction volume (-20.6+/-1.5 cm(3) mol(-1)) has been compared with the difference in partial molar volume of the dienophile (107.8+/-0.2), diene (170.7+/-0.5) and adduct (255.5+/-1.5 cm(3) mol(-1)).
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页码：192 / 193
页数：2
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