The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds

被引:13
|
作者
Chesnokov, S. A. [1 ]
Shurygina, M. P. [1 ]
Abakumov, G. A. [1 ]
机构
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
RADICAL-ION PAIR; ELECTRON-TRANSFER; PICOSECOND DYNAMICS; LASER PHOTOLYSIS; BENZOPHENONE; COMPLEX;
D O I
10.1134/S0018143911040059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A model reaction of hydrogen transfer has been proposed that describes well the results of kinetic studies of the photoreduction of o- and p-quinones and fluorenone in the presence of para-substituted N,N-dimethylanilines and polyalkylbenzenes in various solvents.
引用
收藏
页码:287 / 299
页数:13
相关论文
共 50 条
  • [41] Mechanistic requirements of hydrogen addition to carbonyl compounds
    Lin, Fan
    Shangguan, Junnan
    Wu, Zhenwei
    Chin, Ya-Huei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [42] Hydrogen peroxide, organic peroxides and higher carbonyl compounds determined during the BERLIOZ campaign
    Moortgat, GK
    Grossmann, D
    Boddenberg, A
    Dallmann, G
    Ligon, AP
    Turner, WV
    Gäb, S
    Slemr, F
    Wieprecht, W
    Acker, K
    Kibler, M
    Schlomski, S
    Bächmann, K
    JOURNAL OF ATMOSPHERIC CHEMISTRY, 2002, 42 (01) : 443 - 463
  • [43] Hydrogen Peroxide, Organic Peroxides and Higher Carbonyl Compounds Determined during the BERLIOZ Campaign
    G. K. Moortgat
    D. Grossmann
    A. Boddenberg
    G. Dallmann
    A. P. Ligon
    W. V. Turner
    S. Gäb
    F. Slemr
    W. Wieprecht
    K. Acker
    M. Kibler
    S. Schlomski
    K. Bächmann
    Journal of Atmospheric Chemistry, 2002, 42 : 443 - 463
  • [44] Hydrogen peroxide, organic peroxides and higher carbonyl compounds determined during the BERLIOZ campaign
    Grossmann, D. (dgrossma@sachtleben.de), 1600, Springer Netherlands (42):
  • [45] Revealing Photoinduced Charge Transfer Mechanism of SnO2/BiOBr S-Scheme Heterostructure for CO2 Photoreduction
    An, Yuejiao
    Liu, Wenxuan
    Zhang, Yanfeng
    Zhang, Jianjun
    Lu, Zhansheng
    ACTA PHYSICO-CHIMICA SINICA, 2024, 40 (12)
  • [46] Mechanism of electron transfer processes photoinduced by lumazine
    M. Paula Denofrio
    M. Laura Dántola
    Patricia Vicendo
    Esther Oliveros
    Andrés H. Thomas
    Carolina Lorente
    Photochemical & Photobiological Sciences, 2012, 11 : 409 - 417
  • [47] Mechanism of electron transfer processes photoinduced by lumazine
    Denofrio, M. Paula
    Dantola, M. Laura
    Vicendo, Patricia
    Oliveros, Esther
    Thomas, Andres H.
    Lorente, Carolina
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2002, 1 (12) : 409 - 417
  • [48] ON MECHANISM OF ENERGY TRANSFER FROM N,PI] TRIPLET STATE OF CARBONYL COMPOUNDS TO SIMPLE OLEFINS
    YANG, NC
    COHEN, JI
    SHANI, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (12) : 3264 - &
  • [49] MECHANISM OF PHOTOINDUCED HYDROGENATION OF NORBORNADIENE CATALYZED BY CHROMIUM CARBONYL-COMPLEXES
    PLATBROOD, G
    WILPUTTE.L
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 70 (03) : 393 - 405
  • [50] Photoreduction of azoalkane triplet states by hydrogen atom and charge transfer
    Adam, W
    Moorthy, JN
    Nau, WM
    Scaiano, JC
    JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (25): : 8722 - 8723