The mechanism of photoinduced hydrogen transfer during photoreduction of carbonyl compounds

被引：13
|
作者：
Chesnokov, S. A. [1 ]
Shurygina, M. P. [1 ]
Abakumov, G. A. [1 ]
机构：
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
HIGH ENERGY CHEMISTRY | 2011年 / 45卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
RADICAL-ION PAIR; ELECTRON-TRANSFER; PICOSECOND DYNAMICS; LASER PHOTOLYSIS; BENZOPHENONE; COMPLEX;
D O I：
10.1134/S0018143911040059
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A model reaction of hydrogen transfer has been proposed that describes well the results of kinetic studies of the photoreduction of o- and p-quinones and fluorenone in the presence of para-substituted N,N-dimethylanilines and polyalkylbenzenes in various solvents.
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页码：287 / 299
页数：13
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