Copper(II) Complexes with Apple Pectin Modified with L-Histidine and L-Phenylalanine

被引:0
|
作者
Mudarisova, R. Kh [1 ]
Kukovinets, O. S. [2 ]
Kolesov, S., V [1 ]
机构
[1] Russian Acad Sci, Ufa Fed Res Ctr, Ufa Inst Chem, Ufa 450054, Russia
[2] Bashkir State Univ, Ufa 450078, Russia
关键词
apple pectin; chemical modification; histidine; phenylalanine; complex formation; copper(II); stability constants; INCLUSION COMPLEXES; ANTIANEMIC ACTIVITY; TRYPTOPHAN; BINDING;
D O I
10.1134/S1070363221080156
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New metal-polymer copper(II) complexes based on apple pectin modified with L-histidine and L-phenylalanine were synthesized. The stoichiometry of the resulting complexes and the pH ranges of their existence were determined by spectrophotometric methods. The stability constants and standard thermodynamic characteristics (Delta H degrees, Delta G degrees, Delta S degrees) of the complex formation were calculated. The features of the thermal behavior of copper complexes based on pectin ligands were revealed.
引用
收藏
页码:1533 / 1539
页数:7
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