A highly active Rh1/CeO2 single-atom catalyst for low-temperature CO oxidation

被引：0

作者：

Han, Bing ^{[1
,2
]}

Li, Tianbo ^{[1
,2
]}

Zhang, Junying ^{[3
]}

Zeng, Chaobin ^{[4
]}

Matsumoto, Hiroaki ^{[4
]}

Su, Yang ^{[1
]}

Qiao, Botao ^{[1
,5
]}

Zhang, Tao ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Sci & Technol Appl Catalysis, Dalian 116023, Liaoning, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, State Key Lab Catalysis, Dalian 116023, Peoples R China

[4] Hitachi High Technol Shanghai Co Ltd, Shanghai 201203, Peoples R China

[5] Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 36期

基金：

中国国家自然科学基金;

关键词：

PREFERENTIAL OXIDATION; FTIR SPECTROSCOPY; IN-SITU; RHODIUM; OXIDE; INTERFACE; STABILITY; IDENTIFICATION; IDENTIFY; METHANOL;

D O I：

10.1039/D0CC00230E

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rh-1/CeO2 single-atom catalyst is highly active for CO oxidation and has the potential to serve as a multifunctional catalyst to save the usage of other noble metals in three-way catalysts. The high activity is achieved on single-atom active sites via the Mars-van Krevelen mechanism, thus avoiding CO poisoning at low temperatures.

引用

页码：4870 / 4873

页数：4

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