The preparation of Au/CeO2 catalysts and their activities for low-temperature CO oxidation

被引:22
|
作者
Wang, Xiao-Ying [1 ]
Wang, Shu-Ping [1 ]
Wang, Shu-Rong [1 ]
Zhao, Ying-Qiang [1 ]
Huang, Jing [1 ]
Zhang, Shou-Min [1 ]
Huang, Wei-Ping [1 ]
Wu, Shi-Hua [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
Au/CeO2; catalysts; co-preparation method; deposition-precipitation method; low temperature CO oxidation;
D O I
10.1007/s10562-006-0173-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Au/CeO2 catalysts prepared by co-precipitation (CP) and deposition-precipitation (DP) methods were tested for low temperature CO oxidation reaction. The structural characters and redox features of the catalysts were investigated by XRD, XPS and H-2-TPR. Their catalytic performances for low temperature CO oxidation were studied by means of a microreactor -GC system. It showed that the catalytic activities of Au/CeO2 catalysts greatly depended on the preparation method. The catalysts prepared by DP method exhibited a surprisingly higher activity towards CO oxidation than that prepared by CP method. This may arise from the differences in the particle sizes of Au and redox properties of the catalysts. The low Au loading and the resistance to high temperature of DP-prepared catalyst made it more applicable.
引用
收藏
页码:115 / 119
页数:5
相关论文
共 50 条
  • [1] The preparation of Au/CeO2 catalysts and their activities for low-temperature CO oxidation
    Xiao-Ying Wang
    Shu-Ping Wang
    Shu-Rong Wang
    Ying-Qiang Zhao
    Jing Huang
    Shou-Min Zhang
    Wei-Ping Huang
    Shi-Hua Wu
    [J]. Catalysis Letters, 2006, 112 : 115 - 119
  • [2] Preparation, characterization of CuO/CeO2 and Cu/CeO2 catalysts and their applications in low-temperature CO oxidation
    Zheng, XC
    Han, DZ
    Wang, SP
    Zhang, SM
    Wang, SR
    Haung, WP
    Wu, SH
    [J]. JOURNAL OF RARE EARTHS, 2005, 23 (01) : 47 - 51
  • [3] Preparation, Characterization of CuO/CeO2 and Cu/CeO2 Catalysts and Their Applications in Low-Temperature CO Oxidation
    郑修成
    韩东战
    王淑萍
    张守民
    王淑荣
    黄唯平
    吴世华
    [J]. Journal of Rare Earths, 2005, (01) : 47 - 51
  • [4] In situ preparation and investigation of Pd/CeO2 catalysts for the low-temperature oxidation of CO
    Gulyaev, R. V.
    Stadnichenko, A. I.
    Slavinskaya, E. M.
    Ivanova, A. S.
    Koscheev, S. V.
    Boronin, A. I.
    [J]. APPLIED CATALYSIS A-GENERAL, 2012, 439 : 41 - 50
  • [5] Preparation and characterization of CuO/CeO2 catalysts and their applications in low-temperature CO oxidation
    Zheng, XC
    Zhang, XL
    Wang, XY
    Wang, SR
    Wu, SH
    [J]. APPLIED CATALYSIS A-GENERAL, 2005, 295 (02) : 142 - 149
  • [6] Low-Temperature CO Oxidation by the Pt/CeO2 Based Catalysts
    Stadnichenko, Andrey I.
    Slavinskaya, Elena M.
    Stonkus, Olga A.
    Boronin, Andrei I.
    [J]. CHEMCATCHEM, 2024, 16 (15)
  • [7] Morphology effects of nanoscale ceria on the activity of Au/CeO2 catalysts for low-temperature CO oxidation
    Huang, Xin-Song
    Sun, Hao
    Wang, Lu-Cun
    Liu, Yong-Mei
    Fan, Kang-Nian
    Cao, Yong
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 90 (1-2) : 224 - 232
  • [8] Size-Dependent Reaction Pathways of Low-Temperature CO Oxidation on Au/CeO2 Catalysts
    Chen, Shilong
    Luo, Liangfeng
    Jiang, Zhiquan
    Huang, Weixin
    [J]. ACS CATALYSIS, 2015, 5 (03): : 1653 - 1662
  • [9] Optimizing low-temperature CO oxidation under realistic combustion conditions: The impact of CeO2 morphology on Au/CeO2 catalysts
    Wang, Jing
    Liu, Wei
    Hu, Yandong
    Song, Lei
    Hu, Yuan
    Hou, Yanbei
    Hu, Weizhao
    [J]. Journal of Hazardous Materials, 2025, 487
  • [10] Synergetic effect in PdAu/CeO2 catalysts for the low-temperature oxidation of CO
    R. V. Gulyaev
    L. S. Kibis
    O. A. Stonkus
    A. V. Zadesenets
    P. E. Plyusnin
    Yu. V. Shubin
    S. V. Korenev
    A. S. Ivanova
    E. M. Slavinskaya
    V. I. Zaikovskii
    I. G. Danilova
    A. I. Boronin
    V. A. Sobyanin
    [J]. Journal of Structural Chemistry, 2011, 52 (Suppl 1) : 123 - 136