Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis-[Re(CH3CN)2Cl4] • CH3CN and cis-[Re(NHC(OCH3)CH3)2Cl4]

被引：4
|
作者：
Kunz, Peter C. [1 ]
Kurz, Philipp [1 ]
Spingler, Bernhard [1 ]
Alberto, Roger [1 ]
机构：
[1] Univ Zurich Irchel, Inst Inorgan Chem, CH-8057 Zurich, Switzerland
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 15期
关键词：
rhenium; halogenide abstraction; crystal structures;
D O I：
10.1002/zaac.200700265
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The abstraction of the halogenide ligands in [Re(CH3CN)(2)Cl-4](-) should result in a solvent-only stabilized Re-III complex. The reactions of salts of [Re(CH3CN)(2)Cl-4](-) with silver(1) and thallium(I) salts were investigated and the solid-state structures of cis-[Re(CH3CN)(2)Cl-4] center dot CH3CN and cis[Re(NHC(OCH3)CH3)(2)Cl-4] are described.
引用
收藏
页码：2753 / 2756
页数：4
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