Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis-[Re(CH3CN)2Cl4] • CH3CN and cis-[Re(NHC(OCH3)CH3)2Cl4]

被引：4

作者：

Kunz, Peter C. ^{[1
]}

Kurz, Philipp ^{[1
]}

Spingler, Bernhard ^{[1
]}

Alberto, Roger ^{[1
]}

机构：

[1] Univ Zurich Irchel, Inst Inorgan Chem, CH-8057 Zurich, Switzerland

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 15期

关键词：

rhenium; halogenide abstraction; crystal structures;

D O I：

10.1002/zaac.200700265

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The abstraction of the halogenide ligands in [Re(CH3CN)(2)Cl-4](-) should result in a solvent-only stabilized Re-III complex. The reactions of salts of [Re(CH3CN)(2)Cl-4](-) with silver(1) and thallium(I) salts were investigated and the solid-state structures of cis-[Re(CH3CN)(2)Cl-4] center dot CH3CN and cis[Re(NHC(OCH3)CH3)(2)Cl-4] are described.

引用

页码：2753 / 2756

页数：4

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