Crystal structure of Ba2(CN3H6)[(UO2)2(C2O4)4(NCS)(H2O)]•7H2O

被引：0
|
作者：
Akhmerkina, ZV
Mikhailov, YN
Gorbunova, YE
Serezhkina, LB
Serezhkin, VN
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 02期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of Ba-2(CN3H6)[(UO2)(2)(C2O4)(4)(NCS)(H2O)] . 7H(2)O (I) was studied by X-ray diffraction. The crystals are monoclinic: a = 8.123Angstrom, b = 22.410 Angstrom, c = 18.956 Angstrom, beta = 97.84degrees, Z = 4. The main structural units of crystals of I are mononuclear [UO2(C2O4)(2)(NCS)](3-) and [UO2(C2O4)(2)(H2O)](2-) Complex Species belonging to the AB(2)(01)M(1)(A = UO22+) crystal-chemical group of uranyl complexes, which are combined in a three-dimensional framework by Coulomb interactions with cations and by hydrogen bonds involving water molecules and guanidonium cations.
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页码：167 / 171
页数：5
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