Synthesis and x-ray diffraction of (CN3H6)2[UO2(C2O4)2(H2O)] • H2O

被引：0
|
作者：
Artem'eva, MY
Mikhailov, YN
Gorbunova, YE
Serezhkina, LB
Serezhkin, VN
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 08期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The single crystals of (CN3H6)[UO2(C2O4)(2)(H2O)] center dot H2O (1) were studied by X-ray diffraction. The crystals are monoclinic, a = 7.002(2) angstrom, b = 11.367(2) angstrom, c = 10.846(2) angstrom, beta = 100.71(3)degrees, space group P2/n, Z = 2, R = 0.031. The major structural units of the crystals of I are mononuclear groups [UO2(C2O4)(2)(H2O)](2-), which correspond to the AB(2)(01)M(1) crystal-chemical group (A = UO22+) of uranyl come, plexes. Uranium-containing complexes are connected into a three-dimensional framework by a system of hydrogen bonds involving outer-sphere cations, oxalate ions, and water molecules.
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页码：1173 / 1176
页数：4
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