Crystal structure of Ba2(CN3H6)[(UO2)2(C2O4)4(NCS)(H2O)]•7H2O

被引：0
|
作者：
Akhmerkina, ZV
Mikhailov, YN
Gorbunova, YE
Serezhkina, LB
Serezhkin, VN
机构：
[1] Samara State Univ, Samara 443011, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of Ba-2(CN3H6)[(UO2)(2)(C2O4)(4)(NCS)(H2O)] . 7H(2)O (I) was studied by X-ray diffraction. The crystals are monoclinic: a = 8.123Angstrom, b = 22.410 Angstrom, c = 18.956 Angstrom, beta = 97.84degrees, Z = 4. The main structural units of crystals of I are mononuclear [UO2(C2O4)(2)(NCS)](3-) and [UO2(C2O4)(2)(H2O)](2-) Complex Species belonging to the AB(2)(01)M(1)(A = UO22+) crystal-chemical group of uranyl complexes, which are combined in a three-dimensional framework by Coulomb interactions with cations and by hydrogen bonds involving water molecules and guanidonium cations.
引用
收藏
页码：167 / 171
页数：5
相关论文
共 50 条
  • [31] Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] · 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2] · 6H2O
    I. V. Medrish
    A. V. Virovets
    E. V. Peresypkina
    L. B. Serezhkina
    [J]. Russian Journal of Inorganic Chemistry, 2008, 53 : 1034 - 1039
  • [32] Crystal structure of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] · 1.25H2O
    L. B. Serezhkina
    E. V. Peresypkina
    A. V. Virovets
    N. A. Neklyudova
    D. V. Pushkin
    [J]. Crystallography Reports, 2008, 53 : 651 - 654
  • [33] Synthesis and structures of Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] • 4H2O and (NH4)4[(UO2)2(C2O4)(SO4)2(ncs)2] • 6H2O
    Medrish, I. V.
    Virovets, A. V.
    Peresypkina, E. V.
    Serezhkina, L. B.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (07) : 1034 - 1039
  • [34] Synthesis and crystal structure of [UO2(SO4)(C6H5NO2)2(H2O)] • H2O
    Serezhkina, LB
    Mikhailov, YN
    Gorbunova, YE
    Mit'kovskaya, EV
    Grechishnikova, EV
    Serezhkin, VN
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (08) : 1177 - 1183
  • [35] Geometrical isomerism in uranyl chromates I.: Crystal structures of (UO2)(CrO4)(H2O)2, [(UO2)(CrO4)(H2O)2](H2O) and [(UO2)(CrO4)(H2O)2]4(H2O)9
    Krivovichev, SV
    Burns, PC
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2003, 218 (08): : 568 - 574
  • [36] Synthesis and crystal structure of Ag2[(UO2)6(MoO4)7(H2O)2](H2O)2
    Nazarchuk E.V.
    Siidra O.I.
    Krivovichev S.V.
    [J]. Radiochemistry, 2016, 58 (1) : 1 - 5
  • [37] CRYSTAL STRUCTURE OF H（PyH）3 [MO2o4 （C2o4）2 （H2o）2)2'2H2o
    Yang Rongsheng Yu XiufenInstitute of Structural Chemistry
    [J]. Chinese Journal of Structural Chemistry, 1985, (01) : 1 - 4
  • [38] Crystal Structure of (CN3H6)2[Eu(edta)F(H2O)] • 2H2O
    Mistryukov, V. E.
    Mikhailov, Yu. N.
    Chuklanova, E. B.
    Sergeev, A. V.
    Shchelokov, R. N.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1998, 43 (12) : 1862 - 1864
  • [39] {[Ba2(C2O4)(H2O)6](NCS)2}n:: a layered mixed-anion barium oxalate
    Peresypkina, EV
    Virovets, AV
    Akhmerkina, JV
    Serezhkina, LB
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2004, 60 : M355 - M356
  • [40] Synthesis and X-ray diffraction study of Li(H3O)[UO2(C2O4)2(H2O)] • H2O
    Shilova, M. Yu.
    Vologzhanina, A. V.
    Serezhkina, L. B.
    Serezhkin, V. N.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (11) : 1763 - 1767
12345