Self-assembly and characterization of a novel 2D network polymer containing a 60-membered organotin macrocycle

被引:58
|
作者
Ma, Chunlin [1 ,2 ]
Wang, Qingfeng [1 ]
Zhang, Rufen [1 ]
机构
[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China
[2] Taishan Univ, Tai An 271021, Shandong, Peoples R China
关键词
D O I
10.1021/ic800903s
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of 1-(4-carboxyphenyl)-5-mercapto-1H-tetrazole with trimethyltin chloride in the presence of sodium ethoxide in benzene affords a novel 2D organotin network structure complex 1, which is an unusual organotin network containing a hexanuclear 60-membered organotin macrocycle. The complex has been characterized by elemental analysis, IR, and H-1, C-13, and Sn-119 NMR spectroscopy. Furthermore, we have also characterized the complex by X-ray crystallography.
引用
收藏
页码:7060 / 7061
页数:2
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