Nitro-redox reactions at a frustrated borane/phosphane Lewis pair

被引：5

作者：

Chen, Guo-Qiang ^{[1
]}

Kehr, Gerald ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 16期

基金：

欧洲研究理事会;

关键词：

BORON; HYDROGENATION; ALLYLATION; ACTIVATION; CHEMISTRY; OXIDE; NITROARENES; DERIVATIVES; REAGENTS;

D O I：

10.1039/c6dt00857g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsaturated 1,4-P/B-FLPs 6 reduced nitrobenzene to nitrosobenzene which was directly trapped by an allylboration reaction to give the seven-membered B-O-P compounds 9a and 9b. The FLP 6a reacted analogously with trans-beta-nitrostyrene. The products were characterized by X-ray diffraction.

引用

页码：6820 / 6823

页数：4

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