Synthesis of a Small Cyclic Frustrated Phosphane/Borane Lewis Pair

被引：1
|
作者：
Ugolotti, Juri [1 ,2 ]
Kehr, Gerald [1 ]
Daniliuc, Constantin G. [1 ]
Erker, Gerhard [1 ]
机构：
[1] Westfalische Wilhelms Univ, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany
[2] Palacky Univ, Reg Ctr Adv Technol & Mat, Slechtitelu 27, Olomouc 78371, Czech Republic
来源：
SYNTHESIS-STUTTGART | 2017年 / 49卷 / 01期
基金：
欧洲研究理事会;
关键词：
frustrated Lewis pair; hydroboration; boron; phosphorus; heterocycle; HETEROLYTIC DIHYDROGEN ACTIVATION; FREE CATALYTIC-HYDROGENATION; NOBEL LECTURE; CROWN-ETHERS; CHEMISTRY; BIS(PENTAFLUOROPHENYL)BORANE; HB(C6F5)(2); PHOSPHINES; COMPLEXES; GUESTS;
D O I：
10.1055/s-0036-1588597
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of pyrrolidinodivinylphosphane with three molar equivalents of bis(pentafluorophenyl) borane resulted in the formation of a bicyclic pyrrolidino-bridged P/B frustrated Lewis pair (FLP) derivative, isolated as its P-[HB(C6F5)(2)] adduct. The system can be converted into an unbridged cyclic P/B frustrated Lewis pair derivative by the addition of pyridine.
引用
收藏
页码：53 / 58
页数：6
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