Nitro-redox reactions at a frustrated borane/phosphane Lewis pair

被引：5
|
作者：
Chen, Guo-Qiang [1 ]
Kehr, Gerald [1 ]
Daniliuc, Constantin G. [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 16期
基金：
欧洲研究理事会;
关键词：
BORON; HYDROGENATION; ALLYLATION; ACTIVATION; CHEMISTRY; OXIDE; NITROARENES; DERIVATIVES; REAGENTS;
D O I：
10.1039/c6dt00857g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The unsaturated 1,4-P/B-FLPs 6 reduced nitrobenzene to nitrosobenzene which was directly trapped by an allylboration reaction to give the seven-membered B-O-P compounds 9a and 9b. The FLP 6a reacted analogously with trans-beta-nitrostyrene. The products were characterized by X-ray diffraction.
引用
收藏
页码：6820 / 6823
页数：4
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