Synthesis and Luminescent Property of One New Three-Dimensional {Cd4} Cluster Coordination Polymer Constructed From Multi-Carboxylate Bridging Ligand

被引：1

作者：

Li, Xiao-Ling ^{[1
,2
]}

Zhao, Meng-Lei ^{[1
,2
]}

Yang, Xu-Jia ^{[1
,2
]}

Qiao, Yi-Dan ^{[1
,2
]}

Liu, Guang-Zhen ^{[1
,2
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471934, Henan, Peoples R China

[2] Luoyang Normal Univ, Henan Key Lab Funct Oriented Porous Mat, Luoyang 471934, Henan, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2022年 / 33卷 / 05期

基金：

中国国家自然科学基金;

关键词：

1-benzyl-1; 2; 3-triazole-4; 5-dicarboxylic acid; Cadmium cluster; Fluorescence property; CRYSTAL-STRUCTURE; FRAMEWORKS; COMPLEXES; ACID; CHAINS; SERIES;

D O I：

10.1007/s10876-021-02160-y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reactions of 1-benzyl-1,2,3-triazole-4,5-dicarboxylic acid (H(2)btda) and 5-[4-(1-imidazolyl)phenyl]-2H-tetrazole(ipt) with Cd(Ac)(2)center dot 2H(2)O afford one novel coordination polymer, namely, [Cd-2(btda)(ipt)(2)](n)(1). Complex 1 contains {Cd-4} clusters, exhibiting a 3D metal-organic framework with pcu topology. Furthermore, Powder X-ray diffraction analysis, thermal degeneration and luminescent property of complex 1 is also investigated. Fluorescence measurement show that the target complex 1 has weak luminescent performance.

引用

页码：2305 / 2310

页数：6

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