Synthesis and Luminescent Property of One New Three-Dimensional {Cd4} Cluster Coordination Polymer Constructed From Multi-Carboxylate Bridging Ligand

被引：1
|
作者：
Li, Xiao-Ling [1 ,2 ]
Zhao, Meng-Lei [1 ,2 ]
Yang, Xu-Jia [1 ,2 ]
Qiao, Yi-Dan [1 ,2 ]
Liu, Guang-Zhen [1 ,2 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471934, Henan, Peoples R China
[2] Luoyang Normal Univ, Henan Key Lab Funct Oriented Porous Mat, Luoyang 471934, Henan, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2022年 / 33卷 / 05期
基金：
中国国家自然科学基金;
关键词：
1-benzyl-1; 2; 3-triazole-4; 5-dicarboxylic acid; Cadmium cluster; Fluorescence property; CRYSTAL-STRUCTURE; FRAMEWORKS; COMPLEXES; ACID; CHAINS; SERIES;
D O I：
10.1007/s10876-021-02160-y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solvothermal reactions of 1-benzyl-1,2,3-triazole-4,5-dicarboxylic acid (H(2)btda) and 5-[4-(1-imidazolyl)phenyl]-2H-tetrazole(ipt) with Cd(Ac)(2)center dot 2H(2)O afford one novel coordination polymer, namely, [Cd-2(btda)(ipt)(2)](n)(1). Complex 1 contains {Cd-4} clusters, exhibiting a 3D metal-organic framework with pcu topology. Furthermore, Powder X-ray diffraction analysis, thermal degeneration and luminescent property of complex 1 is also investigated. Fluorescence measurement show that the target complex 1 has weak luminescent performance.
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页码：2305 / 2310
页数：6
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