Photoinduced decarboxylative 1,6-addition of para-quinone methides with α-keto acids: an eco-friendly approach to α,α′-diarylated ketones

被引：6

作者：

He, Chen ^{[1
]}

Zhong, Yingfang ^{[1
]}

Han, Huiqi ^{[1
]}

Wang, Qi ^{[1
]}

Xu, Lijing ^{[1
]}

Zhang, Ting ^{[1
]}

Hu, Yaqiong ^{[1
]}

Huang, Qitong ^{[1
]}

Liu, Jun ^{[2
]}

Yang, Min ^{[1
]}

机构：

[1] Gannan Med Univ, Oil Tea Med Hlth Care & Funct Prod Dev Engn Res Ct, Sch Pharm, Key Lab Biomat & Biofabricat Tissue Engn Jiangxi P, Ganzhou 341000, Peoples R China

[2] Nanchang Univ, Affiliated Ganzhou Hosp, Dept Neurosurg, Ganzhou 341000, Jiangxi, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2022年 / 46卷 / 44期

基金：

中国国家自然科学基金;

关键词：

1,6-CONJUGATE ADDITION; EXPEDIENT ACCESS; P-QMS; ARYLATION; CYCLIZATION; ESTERS; ROUTE; BOND;

D O I：

10.1039/d2nj04562a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoinduced decarboxylative 1,6-addition of para-quinone methides with alpha-keto acids in an eco-friendly approach to alpha,alpha '-diarylated ketones is developed. This reaction proceeds smoothly with a broad substrate scope in the presence of cheap photocatalysts. Some of alpha,alpha '-diarylated ketones were applied as fluorescent dyes into the fluorescence spectrum and live-cell imaging.

引用

页码：21032 / 21036

页数：5

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