Photoinduced decarboxylative 1,6-addition of para-quinone methides with α-keto acids: an eco-friendly approach to α,α′-diarylated ketones

被引：6
|
作者：
He, Chen [1 ]
Zhong, Yingfang [1 ]
Han, Huiqi [1 ]
Wang, Qi [1 ]
Xu, Lijing [1 ]
Zhang, Ting [1 ]
Hu, Yaqiong [1 ]
Huang, Qitong [1 ]
Liu, Jun [2 ]
Yang, Min [1 ]
机构：
[1] Gannan Med Univ, Oil Tea Med Hlth Care & Funct Prod Dev Engn Res Ct, Sch Pharm, Key Lab Biomat & Biofabricat Tissue Engn Jiangxi P, Ganzhou 341000, Peoples R China
[2] Nanchang Univ, Affiliated Ganzhou Hosp, Dept Neurosurg, Ganzhou 341000, Jiangxi, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2022年 / 46卷 / 44期
基金：
中国国家自然科学基金;
关键词：
1,6-CONJUGATE ADDITION; EXPEDIENT ACCESS; P-QMS; ARYLATION; CYCLIZATION; ESTERS; ROUTE; BOND;
D O I：
10.1039/d2nj04562a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photoinduced decarboxylative 1,6-addition of para-quinone methides with alpha-keto acids in an eco-friendly approach to alpha,alpha '-diarylated ketones is developed. This reaction proceeds smoothly with a broad substrate scope in the presence of cheap photocatalysts. Some of alpha,alpha '-diarylated ketones were applied as fluorescent dyes into the fluorescence spectrum and live-cell imaging.
引用
收藏
页码：21032 / 21036
页数：5
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