Forming Mechanism of Dy2Ce2O7 Ceramic for Thermal Barrier Coatings

被引:1
|
作者
Zhang Hongsong [1 ]
Hu Renxi [2 ]
Xu Qiang [3 ]
机构
[1] Henan Inst Engn, Dept Mech & Engn, Zhengzhou 450007, Peoples R China
[2] Ordnance Engn Coll, Dept Basic Courses, Shijiazhuang 050003, Peoples R China
[3] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
来源
CHINESE CERAMICS COMMUNICATIONS | 2010年 / 105-106卷
关键词
Cerium oxides; Solid Reaction; Forming mechanism;
D O I
10.4028/www.scientific.net/AMR.105-106.383
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The forming mechanism of Dy2Ce2O7 prepared by solid reaction using CeO2 and Dy2O3 as reactants was analyzed by X-ray diffraction method. It is indicated that there is almost no solid solution reaction between Dy2O3 and CeO2 before 1300 degrees C, the Dy3+ cations enter the crystal lattice of CeO2 and substitute sites of Ce4+ cations in the range between 1300 degrees C and 1400 degrees C which resulted in the formation of Dy2O3-CeO2 solid solution. The Dy2O3-CeO2 solid solution transformed gradually into Dy2Ce2O7 after 1400 degrees C and pure Dy2Ce2O7 can be obtained at 1500 degrees C. No other intermediate phases were found in the whole process.
引用
收藏
页码:383 / +
页数:2
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