Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acrylic Acid in Water: One-Step Preparation of 3-Arylpropionic Acids

被引：12
|
作者：
Vautravers, Nicolas R. [1 ]
Breit, Bernhard [1 ]
机构：
[1] Univ Freiburg, Inst Organ Chem & Biochem, Freiburg Inst Adv Studies FRIAS, D-79104 Freiburg, Germany
来源：
SYNLETT | 2011年 / 17期
关键词：
boronic acids; acrylic acid; water; conjugate addition; rhodium; CATALYZED ASYMMETRIC 1,4-ADDITION; CONJUGATE ADDITION; ENANTIOSELECTIVE DESYMMETRIZATION; ALLYLIC AMINES; BORONIC ACIDS; RHODIUM; ALKYNES; HETEROCYCLES; REAGENTS; LIGANDS;
D O I：
10.1055/s-0030-1260319
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical method for the one-step preparation of 3-arylpropionic acids through rhodium-catalyzed 1,4-addition of arylboronic acids to acrylic acid is reported. The method is applicable to a broad scope of aryl boronic acids and displays a wide functional group tolerance operating in water as the optimal reaction medium.
引用
收藏
页码：2517 / 2520
页数：4
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