BICMAP-rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins

被引：8
|
作者：
Mino, Takashi [1 ,2 ]
Miura, Kazuki [1 ]
Taguchi, Hiroyuki [1 ]
Watanabe, Kohei [1 ]
Sakamoto, Masami [1 ,2 ]
机构：
[1] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 2638522, Japan
[2] Chiba Univ, Mol Chiral Res Ctr, Inage Ku, Chiba 2638522, Japan
来源：
TETRAHEDRON-ASYMMETRY | 2015年 / 26卷 / 18-19期
基金：
日本学术振兴会;
关键词：
CONJUGATE ADDITIONS; LIGANDS;
D O I：
10.1016/j.tetasy.2015.08.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids 2 to coumarins 1 using (S)-BICMAP as a chiral ligand gave the desired 4-arylchroman-2-one derivatives 2 in good yields and with high enantioselectivities (up to 99% ee). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1065 / 1068
页数：4
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