BICMAP-rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins

被引：8

作者：

Mino, Takashi ^{[1
,2
]}

Miura, Kazuki ^{[1
]}

Taguchi, Hiroyuki ^{[1
]}

Watanabe, Kohei ^{[1
]}

Sakamoto, Masami ^{[1
,2
]}

机构：

[1] Chiba Univ, Grad Sch Engn, Dept Appl Chem & Biotechnol, Inage Ku, Chiba 2638522, Japan

[2] Chiba Univ, Mol Chiral Res Ctr, Inage Ku, Chiba 2638522, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2015年 / 26卷 / 18-19期

基金：

日本学术振兴会;

关键词：

CONJUGATE ADDITIONS; LIGANDS;

D O I：

10.1016/j.tetasy.2015.08.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium(I)-catalyzed asymmetric 1,4-addition of arylboronic acids 2 to coumarins 1 using (S)-BICMAP as a chiral ligand gave the desired 4-arylchroman-2-one derivatives 2 in good yields and with high enantioselectivities (up to 99% ee). (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：1065 / 1068

页数：4

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