Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to α,β-unsaturated esters

被引：155

作者：

Takaya, Y ^{[1
]}

Senda, T ^{[1
]}

Kurushima, H ^{[1
]}

Ogasawara, M ^{[1
]}

Hayashi, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 20期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/S0957-4166(99)00417-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of arylboron reagents, arylboronic acids or arylborates, which are readily accessible by lithiation of aryl bromides followed by treatment with trimethoxyborane, with alpha,beta-unsaturated esters in the presence of rhodium/(S)-binap catalyst proceeded with high enantioselectivity to give high yields of optically active beta-aryl esters of up to 98% ee. The enantioselectivity depends on the steric bulkiness of the ester moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4047 / 4056

页数：10

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