Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acrylic Acid in Water: One-Step Preparation of 3-Arylpropionic Acids

被引：12

作者：

Vautravers, Nicolas R. ^{[1
]}

Breit, Bernhard ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, Freiburg Inst Adv Studies FRIAS, D-79104 Freiburg, Germany

来源：

SYNLETT | 2011年 / 17期

关键词：

boronic acids; acrylic acid; water; conjugate addition; rhodium; CATALYZED ASYMMETRIC 1,4-ADDITION; CONJUGATE ADDITION; ENANTIOSELECTIVE DESYMMETRIZATION; ALLYLIC AMINES; BORONIC ACIDS; RHODIUM; ALKYNES; HETEROCYCLES; REAGENTS; LIGANDS;

D O I：

10.1055/s-0030-1260319

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical method for the one-step preparation of 3-arylpropionic acids through rhodium-catalyzed 1,4-addition of arylboronic acids to acrylic acid is reported. The method is applicable to a broad scope of aryl boronic acids and displays a wide functional group tolerance operating in water as the optimal reaction medium.

引用

页码：2517 / 2520

页数：4

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