Synthesis and characterization of novel polyvalent organoiodine compounds

被引：28
|
作者：
Meprathu, BV
Protasiewicz, JD [1 ]
机构：
[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA
[2] Case Western Reserve Univ, Ctr Canc, Cleveland, OH 44106 USA
来源：
ARKIVOC | 2003年
关键词：
polyvalent organoiodine compounds; PhINTs; PhIO; secondary bonding;
D O I：
10.3998/ark.5550190.0004.610
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis and characterization of soluble analogues of iodosylbenzene PhIO and (tosyliminoiodo) benzene PhINTs are reported. The syntheses of 4-trifluoromethyl-2-(tertbutylsulfonyl) iodosylbenzene (3) and 4-trifluoromethyl- 2-(tert-butylsulfonyl)( tosylimino) iodobenzene ( 4) increase the repertoire of available soluble organoiodine(III) based oxo- and nitrene precursors. We also report the synthesis of a new organoiodine( V) compound, 4-trifluoromethyl- 2-( tert-butylsulfonyl) iodylbenzene.
引用
收藏
页码：83 / 90
页数：8
相关论文
共 50 条
  • [41] Synthesis and characterization of organosilicon compounds as novel precursors for CVD processes
    Ermakova, E. N.
    Sysoev, S. V.
    Nikulina, L. D.
    Tsyrendorzhieva, I. P.
    Rakhlin, V. I.
    Kosinova, M. L.
    THERMOCHIMICA ACTA, 2015, 622 : 2 - 8
  • [42] Synthesis and Characterization of Novel Transition Metal Pnictogenide Compounds.
    Dollberg, Kevin
    Moritz, Jan
    Meszaros, Katalin
    Jakobi, Celina
    Richter, Roman-Malte
    Weigend, Florian
    von Haenisch, Carsten
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2024, 650 (11-12):
  • [43] The synthesis and spectral characterization of novel nitrodiene compounds from thiols
    Ibis, Cemil
    Ozkok, Funda
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2016, 191 (01) : 9 - 15
  • [44] Synthesis and characterization of novel stilbenophanes: the smallest members of this class of compounds
    Darabi, HR
    Mohebbi, AR
    Bolourtchian, M
    SUPRAMOLECULAR CHEMISTRY, 2003, 15 (06) : 465 - 468
  • [45] Novel Flurbiprofen-iminothiazoline Hybrid Compounds: Synthesis and Characterization
    Saeed, Aamer
    Shabbir, Saira
    Floerke, Ulrich
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2016, 53 (05) : 1395 - 1401
  • [46] Carboiodanation of Arynes: Organoiodine(III) Compounds as Nucleophilic Organometalloids
    Arakawa, Chisaki
    Kanemoto, Kazuya
    Nakai, Katsuya
    Wang, Chen
    Morohashi, Shunya
    Kwon, Eunsang
    Ito, Shingo
    Yoshikai, Naohiko
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (06) : 3910 - 3919
  • [47] A new source of volatile organoiodine compounds in surface seawater
    Martino, Manuela
    Mills, Graham P.
    Woeltjen, Janina
    Liss, Peter S.
    GEOPHYSICAL RESEARCH LETTERS, 2009, 36
  • [48] Organic polyvalent iodine compounds
    Stang, PJ
    Zhdankin, VV
    CHEMICAL REVIEWS, 1996, 96 (03) : 1123 - 1178
  • [49] ORGANIC POLYVALENT IODINE COMPOUNDS
    BANKS, DF
    CHEMICAL REVIEWS, 1966, 66 (03) : 243 - &
  • [50] Aliphatic compounds of polyvalent iodine
    Thiele, J
    Peter, W
    JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1909, 369 (1/3): : 119 - 130
12345