Synthesis and characterization of novel polyvalent organoiodine compounds

被引：28
|
作者：
Meprathu, BV
Protasiewicz, JD [1 ]
机构：
[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA
[2] Case Western Reserve Univ, Ctr Canc, Cleveland, OH 44106 USA
来源：
ARKIVOC | 2003年
关键词：
polyvalent organoiodine compounds; PhINTs; PhIO; secondary bonding;
D O I：
10.3998/ark.5550190.0004.610
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis and characterization of soluble analogues of iodosylbenzene PhIO and (tosyliminoiodo) benzene PhINTs are reported. The syntheses of 4-trifluoromethyl-2-(tertbutylsulfonyl) iodosylbenzene (3) and 4-trifluoromethyl- 2-(tert-butylsulfonyl)( tosylimino) iodobenzene ( 4) increase the repertoire of available soluble organoiodine(III) based oxo- and nitrene precursors. We also report the synthesis of a new organoiodine( V) compound, 4-trifluoromethyl- 2-( tert-butylsulfonyl) iodylbenzene.
引用
收藏
页码：83 / 90
页数：8
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