Ionothermal Synthesis of an Aluminophosphate Molecular Sieve with 20-Ring Pore Openings

被引:113
|
作者
Wei, Ying [1 ,2 ]
Tian, Zhijian [1 ]
Gies, Hermann [3 ]
Xu, Renshun [1 ,2 ]
Ma, Huaijun [1 ]
Pei, Renyan [1 ,2 ]
Zhang, Weiping [1 ]
Xu, Yunpeng [1 ]
Wang, Lei [1 ]
Li, Keda [1 ,2 ]
Wang, Bingchun [1 ]
Wen, Guodong [1 ,2 ]
Lin, Liwu [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
基金
中国国家自然科学基金;
关键词
aluminophosphates; -CLO structure; extralarge pores; ionic liquids; zeolite analogues; METAL-ORGANIC FRAMEWORKS; IONIC LIQUIDS; ZEOLITE; CLOVERITE; RINGS;
D O I
10.1002/anie.201000320
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Figure Presented Open for business: The first aluminophosphate molecular sieve with 20-ring pore openings has been synthesized ionothermally using a co-structure-directing agent (see figure; H white, C turquoise, N blue). The new material has a -CLO framework and excellent stability in comparison to the QaPO4 analogue cloverite. These characteristics indicate its potential applications in separation, catalysis, and gas storage. © 2010 Wiley-VCH Verlag GmbH & Co. KCaA,.
引用
收藏
页码:5367 / 5370
页数:4
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