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Ionothermal Synthesis of an Aluminophosphate Molecular Sieve with 20-Ring Pore Openings
被引:113
|作者:
Wei, Ying
[1
,2
]
Tian, Zhijian
[1
]
Gies, Hermann
[3
]
Xu, Renshun
[1
,2
]
Ma, Huaijun
[1
]
Pei, Renyan
[1
,2
]
Zhang, Weiping
[1
]
Xu, Yunpeng
[1
]
Wang, Lei
[1
]
Li, Keda
[1
,2
]
Wang, Bingchun
[1
]
Wen, Guodong
[1
,2
]
Lin, Liwu
[1
]
机构:
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
基金:
中国国家自然科学基金;
关键词:
aluminophosphates;
-CLO structure;
extralarge pores;
ionic liquids;
zeolite analogues;
METAL-ORGANIC FRAMEWORKS;
IONIC LIQUIDS;
ZEOLITE;
CLOVERITE;
RINGS;
D O I:
10.1002/anie.201000320
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Figure Presented Open for business: The first aluminophosphate molecular sieve with 20-ring pore openings has been synthesized ionothermally using a co-structure-directing agent (see figure; H white, C turquoise, N blue). The new material has a -CLO framework and excellent stability in comparison to the QaPO4 analogue cloverite. These characteristics indicate its potential applications in separation, catalysis, and gas storage. © 2010 Wiley-VCH Verlag GmbH & Co. KCaA,.
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页码:5367 / 5370
页数:4
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