Anionic or neutral? the charge of Ni8 cubes in metal-organic framework compounds

被引：3
|
作者：
Freund, Ralph [1 ]
Kalytta-Mewes, Andreas [1 ]
Kraft, Maryana [1 ]
Volkmer, Dirk [1 ]
机构：
[1] Univ Augsburg, Inst Phys, Chair Solid State & Mat Chem, Univ Str 1, D-86159 Augsburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 67期
关键词：
CAPTURE;
D O I：
10.1039/d2cc03016k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cubic SBU Ni8X6L6 (X = OH-/H2O, L = ligand) is of great interest due to its stability and potential applications when integrated in MOFs. Here, we investigate by detailed DRIFTS measurements and exchange reactions whether it is found to be neutral in MOFs, as previously assumed in the literature, or whether it can show anionic character, as observed in complexes.
引用
收藏
页码：9349 / 9352
页数：4
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