FeIII/FeII regular charge order in metal-organic framework

被引：34
|
作者：
Medina, Manuela Eloisa [1 ]
Dumont, Yves [2 ]
Grenechec, Jean-Marc [3 ]
Millange, Franck [1 ]
机构：
[1] Univ Versailles St Quentin En Yvelines, Inst Lavoisier, UMR 8180, CNRS, F-78035 Versailles, France
[2] Univ Versailles St Quentin En Yvelines, GEMaC, UMR 8635, CNRS, F-78035 Versailles, France
[3] Univ Maine, LPEC, UMR 6087, CNRS, F-72085 La Mans, France
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 42期
关键词：
MIL-53(FE); ADSORPTION; MOLECULES; SORPTION; CHAINS;
D O I：
10.1039/c0cc02161j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrolysis of the DMF solvent (DMF = N,N'-dimethylformamide) generates in situ the template cations DMA(+) (dimethylammonium cation): it leads to the first MOF type solid (Fe0.5Fe0.5II)-Fe-III(OH,F)(O2C-C6H4-CO2)center dot 0.5DMA with a regular charge order Fe-III/Fe-II and an anionic framework with pores filled by counter-cations which behaves as a quasi-1D AF system with alternate localized Fe-II and Fe-III moments.
引用
收藏
页码：7987 / 7989
页数：3
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