Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]•2.5H2O

被引：4
|
作者：
Zavakhina, M. S. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 01期
关键词：
copper; coordination polymers; metal-organic frameworks; chiral complexes; malic acid; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES;
D O I：
10.1134/S0022476615010151
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu-2(S-mal)(2)(bpy)(2)(H2O)]center dot 2.5H(2)O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
引用
收藏
页码：108 / 112
页数：5
相关论文
共 50 条
  • [31] Synthesis and crystal structure of Cu2(pba)(bpy)2Cl2•4H2O
    Zhu, ZC
    Mao, XP
    Xu, Z
    Huang, XY
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (05) : 322 - 325
  • [32] Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] • H2O}n
    Tao, RJ
    Li, FA
    Cheng, YX
    Zang, SQ
    Wang, QL
    Niu, JY
    Liao, DZ
    INORGANICA CHIMICA ACTA, 2006, 359 (07) : 2053 - 2058
  • [33] Synthesis, Crystal Structure and Thermal Stability Properties of a Binuclear Copper(II) Coordination Polymer {[Cu2(4,4′-bipy)2(o-ABA)4(H2O)2][(H2O)2]}n
    Liu Ting
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (02) : 195 - 198
  • [34] Synthesis, spectral, thermal and structural characterization of {[Cu(H2O)3][Cu(MAL)2] · 2H2O}∞ and [Cu(MAL)(TEA)] · H2O (MAL = malonate and TEA = triethanolamine)
    Veysel T. Yilmaz
    Evrim Senel
    Carsten Thöne
    Transition Metal Chemistry, 2004, 29 : 336 - 342
  • [35] Synthesis and crystal structure of {Cu2(pdc)2(4,4′-bipy)(H2O)•3H2O}2
    Wen, YH
    Zhang, J
    Qin, YY
    Li, ZH
    Yao, K
    Chen, YB
    Cheng, HK
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (09) : 1001 - 1004
  • [36] Synthesis, spectral, thermal and structural characterization of{[Cu(H2O)3][Cu(MAL)2]•2H2O}∞ and [Cu(MAL)(TEA)]•H2O (MAL = malonate and TEA = triethanolamine)
    Yilmaz, VT
    Senel, E
    Thöne, C
    TRANSITION METAL CHEMISTRY, 2004, 29 (03) : 336 - 342
  • [37] Synthesis and Crystal Structure of {Cu2（pdc）2（4,4'-bipy）(H2O)·3H2O}2
    WEN Yi-Hang ZHANG Jian QIN Ye-Yan LI Zhao-Ji KANG Yao CHEN Yu-Biao CHENG Jian-Kai YAO Yuan-Gen② (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2004, (09) : 1001 - 1004
  • [38] Synthesis and Structure of a Novel Compound [Cu2（EDTA）(Py)2（H2O）2]·2H2O
    TANG Ding-Xinga② ZHAO Yunb (a: Department of Biochemical Engineering
    Chinese Journal of Structural Chemistry, 2005, (03) : 307 - 310
  • [39] Synthesis and structure of a novel compound [Cu2(EDTA)(Py)2(H2O)2]•2H2O
    Tang, DX
    Zhao, Y
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (03) : 307 - 310
  • [40] Synthesis and Crystal Structure of a Bipy Bridged Binuclear CuⅡ Complex Containing Aminomethanesulfonic Acid [Cu2(Sams)2(Bipy)(H2O)2]·(H2O)
    蔡成翔
    何坤欢
    蒋毅民
    Chinese Journal of Structural Chemistry, 2009, 28 (10) : 1275 - 1280
12345