Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]•2.5H2O

被引:4
|
作者
Zavakhina, M. S. [1 ,2 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
关键词
copper; coordination polymers; metal-organic frameworks; chiral complexes; malic acid; METAL-ORGANIC FRAMEWORKS; TOPOLOGIES;
D O I
10.1134/S0022476615010151
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu-2(S-mal)(2)(bpy)(2)(H2O)]center dot 2.5H(2)O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
引用
收藏
页码:108 / 112
页数:5
相关论文
共 50 条
  • [1] Crystal structure of the coordination polymer [Cu2(S-mal)2(bpy)2(H2O)]·2.5H2O
    M. S. Zavakhina
    D. G. Samsonenko
    V. P. Fedin
    Journal of Structural Chemistry, 2015, 56 : 108 - 112
  • [2] Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu2(tpt)(bpy)2(H2O)4] [Cu2(tpt)3 (bpy)2(H2O)2]
    Bu, PY
    Zhang, LZ
    Li, LC
    Cheng, P
    Yan, SP
    Jiang, ZH
    Liao, DZ
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (04) : 257 - 262
  • [3] Synthesis and crystal structure of a terephthalato-bridged copper(II) complex [Cu2(tpt)(bpy)2(H2O)4] [Cu2(tpt)3 (bpy)2(H2O)2]
    Ping-Yu Bu
    Lei Z. Zhang
    Li-Cun Li
    Peng Cheng
    Shi-Ping Yan
    Zong-Hui Jiang
    Dai-Zheng Liao
    Journal of Chemical Crystallography, 2003, 33 : 257 - 262
  • [4] Ferromagnetism in malonato-bridged copper(II) complexes.: Synthesis, crystal structures, and magnetic properties of {[Cu(H2O)3][Cu(mal)2(H2O)]}n and {[Cu(H2O)4]2[Cu(mal)2(H2O)]}[Cu(mal)2(H2O)2]{[Cu(H2O)4][Cu(mal)2(H2O)2]} (H2mal = malonic acid)
    Ruiz-Pérez, C
    Sanchiz, J
    Molina, MH
    Lloret, F
    Julve, M
    INORGANIC CHEMISTRY, 2000, 39 (07) : 1363 - 1370
  • [5] Copper(II) malonate coordination frameworks with amino-1,2,4-triazole: Crystal structures and magnetic properties of [Cu2(mal)2(datz)2(H2O)]·5H2O and [Cu2(mal)2(atz)2(H2O)]·3H2O
    E. N. Nfor
    E. A. Eno
    J. N. Foba-Tendo
    G. E. Iniama
    E. O. Duke
    O. E. Offiong
    Journal of Structural Chemistry, 2012, 53 : 1118 - 1124
  • [6] CRYSTAL STRUCTURE OF METAL-ORGANIC COORDINATION POLYMERS [Cu(bpy)2(H2O)2](NO3)2•4.5C2H5OH AND [Cu2(bpy)(H2O)(L-pha)2](NO3)2•H2O
    Yutkin, M. P.
    Zavakhina, M. S.
    Samsonenko, D. G.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (02) : 365 - 370
  • [7] Copper(II) malonate coordination frameworks with amino-1,2,4-triazole: Crystal structures and magnetic properties of [Cu2(mal)2(datz)2(H2O)]•5H2O and [Cu2(mal)2(atz)2(H2O)]•3H2O
    Nfor, E. N.
    Eno, E. A.
    Foba-Tendo, J. N.
    Iniama, G. E.
    Duke, E. O.
    Offiong, O. E.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (06) : 1118 - 1124
  • [8] Synthesis, crystal structure and magnetic properties of [Cu(bpym)(mal)(H2O)]•6H2O and [Cu2(bpym)(mal)2(H2O)2]•4H2O (bpym = 2,2′-bipyrimidine, H2mal = malonic acid)
    Rodríguez-Martín, Y
    Sanchiz, J
    Ruiz-Pérez, C
    Lloret, F
    Julve, M
    INORGANICA CHIMICA ACTA, 2001, 326 (01) : 20 - 26
  • [9] Crystal structures of [Cu2(bpy)2(H2O)(OH)2(SO4)] • 4H2O and [Cu(bpy)(H2O)2]SO4 with bpy=2,2′-bipyridine
    Zheng, YQ
    Lin, JL
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (09): : 1622 - 1626
  • [10] Crystal Structure and Magnetic Properties of a Novel Helical Coordination Polymer [Cu2(pda)2(phen)2(H2O)2]•6H2O
    Zhang, Meili
    Wu, Yapan
    Wang, Jijiang
    Ren, Yixia
    Hou, Xiangyang
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2010, 20 (04) : 862 - 866