Microwave-Assisted Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides in Water

被引：25
|
作者：
Chen, Yi-An [1 ]
Badsara, Satpal Singh [1 ]
Tsai, Wan-Ting [1 ]
Lee, Chin-Fa [1 ]
机构：
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
来源：
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 02期
关键词：
microwave heating; copper; cross-coupling; thiols; aryl iodides; sulfides; S BOND FORMATION; C-H FUNCTIONALIZATION; LIGAND-FREE; EFFICIENT SYNTHESIS; METAL-FREE; ORGANIC-SYNTHESIS; TE BOND; HALIDES; SULFUR; CONVENIENT;
D O I：
10.1055/s-0034-1379206
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Microwave-promoted C-S bond formation from thiols and aryl iodides in the presence of a copper catalyst is reported. A combination of copper(II) oxide and 1,10-phenanthroline catalyzes this reaction. A variety of aryl iodides react smoothly with thiols to provide the corresponding aryl sulfides in good to excellent yields. Notably, the reactions proceed in water with a short reaction time (30 minutes). This system shows broad functional-group tolerance; amino, chloro, bromo, acetyl, and nitro groups are unaffected by the reaction conditions.
引用
收藏
页码：181 / 186
页数：6
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