Hydrothermal synthesis and characterization of a zinc-cobalt phosphate microporous material

被引：6
|
作者：
Liu, L [1 ]
Meng, H [1 ]
Li, GH [1 ]
Cui, YJ [1 ]
Ding, H [1 ]
Xing, Y [1 ]
Pang, WQ [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
MATERIALS LETTERS | 2005年 / 59卷 / 14-15期
基金：
中国国家自然科学基金;
关键词：
zinc-cobalt phosphate; hydrothermal synthesis; crystal structure; XRD; magnetic materials;
D O I：
10.1016/j.matlet.2005.01.059
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new zinc-cobalt phosphate compound [Zn(4-x)COx(PO4)(2)(HPO4)][C3H4N2](3) (x=0.25) (1) has been hydrothermally synthesized in the presence of imidazole as the template and crystallizes in the triclinic space group P-1 with crystal data a=9.6077(7) angstrom, b=9.8674(7) angstrom, c=12.3793(9) angstrom, alpha=77.569(4)degrees, beta=78.040(4)degrees, gamma=68.191(4)degrees, V=1053.52(13) angstrom(3), Z=2. Compound 1 exhibits an infinite two-dimensional layered structure, which is built up Of {M8P6O23} structural unit formed by vertex-sharing MO4, MO2N2, MO3N, PO4 and PO3(OH) (M=Zn, Co) moieties. A study of magnetic measurements indicates compound I has the well antiferromagnetic behavior. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1752 / 1755
页数：4
相关论文
共 50 条
  • [21] Electrowinning of anticorrosive zinc-cobalt alloy coatings
    Nawrat, Ginter
    Maciej, Artur
    Piotrowski, Jerzy
    OCHRONA PRZED KOROZJA, 2010, 53 (4-5): : 262 - 265
  • [22] THE ELECTROCHEMICAL PROPERTIES OF ELECTRODEPOSITED ZINC-COBALT ALLOYS
    LEIDHEISER, H
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (08) : C325 - C325
  • [23] ON THE CATIONIC DISTRIBUTION IN ZINC-COBALT OXIDE SPINELS
    KREZHOV, K
    KONSTANTINOV, P
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1993, 5 (50) : 9287 - 9294
  • [24] Texture and Surface Morphology Development in Zinc and Zinc-Cobalt Electrodeposits
    Raeissi, K.
    Tufani, A.
    Saatchi, A.
    Golozar, M. A.
    Szpunar, J. A.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (12) : D783 - D790
  • [25] Synthesis, structure and characterization of ZrPOF-DEA, a microporous zirconium phosphate framework material
    Kubli, Martin
    Sisak, Dubravka
    Baerlocher, Christian
    McCusker, Lynne B.
    Liu, Lei
    Yang, Jiangfeng
    Li, Jinping
    Dong, Jinxiang
    MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 164 : 82 - 87
  • [26] Conversion coatings for zinc-cobalt alloy electrodeposits
    Michael, MS
    Pushpavanam, M
    Balakrishnan, K
    BULLETIN OF ELECTROCHEMISTRY, 1996, 12 (1-2): : 80 - 82
  • [27] Texture and morphology development in zinc-cobalt electrodeposition
    Tufani, A.
    Raeissi, K.
    Saatchi, A.
    Szpunar, J. A.
    TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 2009, 87 (01): : 45 - 50
  • [28] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF COBALT CLAYS
    BRUCE, LA
    SANDERS, JV
    TURNEY, TW
    CLAYS AND CLAY MINERALS, 1986, 34 (01) : 25 - 36
  • [29] HYDROTHERMAL SYNTHESIS OF NANO-METER MICROPOROUS ZINC FERRITE
    Xiaoling Hu*
    Particuology, 2004, (03) : 135 - 137
  • [30] Hydrothermal synthesis of zinc-cobalt binary hydroxide / reduced graphene oxide composite nanosheets as electrode materials with surface redox pseudocapacitive behaviour
    Rose, Aleena
    Jayachandran, M.
    Vijayakumar, T.
    SURFACES AND INTERFACES, 2024, 44
12345