Solvothermal Synthesis, Crystal Structures, and Magnetic Properties of Two Organically Templated Iron Sulfates with Chain Structures

被引：2
|
作者：
Ma, Ling [1 ]
Liu, Dan [2 ]
Xing, Yan [1 ]
Liu, Xianchun [1 ]
Li, Gaijuan [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 15期
关键词：
Iron; Sulfates; Chain structures; Solvothermal synthesis; X-ray diffraction; HYDROTHERMAL SYNTHESIS; METAL SULFATES; KAGOME; NETWORK; HYBRID;
D O I：
10.1002/zaac.201000152
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new one-dimensional (ID) organically templated iron(III) sulfates [C2NH8](3) [Fe-3(mu(3)-O)(2)(SO4)(4)] (1) and [C2N2H10][C2NH7](0.5)[FeF(SO4)(2)] (2) were synthesized under solvo-thermal conditions and characterized by single-crystal X-ray diffraction, powder X-ray diffraction (XRD), FT-IR spectroscopy, elemental analyses, ICP analyses, and thermogravimetric analyses. Single-crystal structure analysis reveals that both compounds show linear-chain structures, involving FeO6 (FeF2O4) octahedra and SO4 tetrahedra. The magnetic properties of the two compounds have also been investigated.
引用
收藏
页码：2681 / 2685
页数：5
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