Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates

被引：4
|
作者：
Fu, Jie [1 ]
Zheng, Lei [1 ]
Yuan, Yan [1 ]
Song, You [2 ]
Xu, Yan [1 ]
机构：
[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Hydrothermal synthesis; Lanthanide sulfates; Crystal structures; Magnetic property; SOLVOTHERMAL SYNTHESIS; EUROPIUM SULFATE; METAL SULFATES; LUMINESCENCE; CHAINS;
D O I：
10.1007/s10870-011-0166-8
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Two new lanthanide sulfates [C6H14N2](2)[Ln(2)(SO4)(4)(H2O)(4)][SO4]center dot 6H(2)O (Ln = Pr 1, Nd 2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Single crystal X-ray diffraction illuminates that both 1 and 2 crystallize in orthorhombic crystal system, space group Pbna with cell dimensions: a = 10.1362(13) , b = 13.4782(17) , c = 25.565(3) , V = 3492.6(8) (3), Z = 4 for 1; a = 10.1243(12) , b = 13.4438(16) , c = 25.550(3) , V = 3477.6(7) (3), Z = 4 for 2. Structure analysis indicates that both 1 and 2 are layered structures and the sulfate ions as well as the organic templates reside among the layers. Magnetic property of compound 1 was investigated further.
引用
收藏
页码：1737 / 1741
页数：5
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