Low-temperature oxidation of sulfur dioxide by molecular oxygen in aqueous solutions of non-transition metals trifluoroacetates

被引：0
|
作者：
Vishnetskaya, M. V. [1 ]
Murtazina, Yu. V. [1 ]
Skrepleva, I. Yu. [2 ]
Mel'nikov, M. Ya. [2 ]
机构：
[1] Gubkin State Univ Oil & Gas, Moscow, Russia
[2] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
molecular oxygen; active state; Bronsted acidity; oxidation; alkali metal; trifluoroacetates; ALKANES; ACID;
D O I：
10.1134/S0036024411050311
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Oxidation of SO(2) was shown to occur in aqueous solutions of Li, Na, and K trifluoroacetates at room temperature. Oxidative activity of the non-transition metal trifluoroacetates increases on decreasing pH of solution and at equal pH values, it follows the sequence: Li < Na < K.
引用
收藏
页码：777 / 779
页数：3
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