meso-tetraphenylporphyrinatocobalt(II) nitrosyl complex in low-temperature sublimates:: Oxidation with molecular oxygen

被引:0
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作者
Kurtikyan, TS [1 ]
机构
[1] Armenian Res Inst Appl Chem ARIAK, Yerevan, Armenia
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
IR spectroscopy was used to show that meso-tetraphenylporphyrinatocobalt(II) nitrosyl complex (ON)CoTPP, prepared by the direct action of nitrogen oxide on the low-temperature sublimated CoTPP layer, slowly converts into the pentacoordination nitro complex (O2N)(CoTPP)-T-III in the oxygen atmosphere.
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页码:28 / 30
页数:3
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