Organic-inorganic hybrid materials doped with lithium ions

被引:0
|
作者
Zelazowska, Elzbieta [1 ]
Borczuch-Laczka, Maria [2 ]
Rysiakiewicz-Pasek, Ewa [3 ]
机构
[1] Inst Glass & Ceram, Cracow Branch, Ul Lipowa 3, PL-30702 Krakow, Poland
[2] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland
[3] Wroclaw Univ Technol, Inst Phys, PL-50370 Wroclaw, Poland
关键词
organic-inorganic hybrids; lithium-ion conductivity; sol-gel;
D O I
暂无
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Organic-inorganic hybrid materials have been synthesized by the sol-gel method, using tetraethyl orthosilicate (TEOS), poly(ethylene oxide) (PEO), net-polyacrylic-inter-net-polysiloxane, butyl acrylate, ethyl acetoacetate, tetrahydrofuran, acetonitrile and LiClO4 precursors and additives. Mass fractions of the organic additions in the gels were of ca 35-40 mass%. The hybrid materials obtained were amorphous, colourless, transparent or translucent, with room temperature ionic conductivities in a range of 10(-4_)10(-3) Omega(-1)cm(-1). The results of scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM/EDX), Fourier transform infrared spectroscopy and Si-29 MAS Nuclear Magnetic Resonance analysis have revealed [SiO4] tetrahedrons polycondensation strongly influenced by organic precursors and chemical bonding between organic and inorganic parts of the gels obtained.
引用
收藏
页码:137 / 146
页数:10
相关论文
共 50 条
  • [41] Catalytic applications of organic-inorganic hybrid porous materials
    Wang, Maodi
    Dai, Huicong
    Yang, Qihua
    Chemical Communications, 2024, 60 (91) : 13325 - 13335
  • [42] Replication of microoptical elements in hybrid organic-inorganic materials
    Topart, P
    Beaulieu, R
    Leclair, S
    Poirier, M
    Pelletier, J
    Bernier, M
    Jerominek, H
    MICROMACHINING TECHNOLOGY FOR MICRO-OPTICS AND NANO-OPTICS, 2003, 4984 : 54 - 62
  • [43] Hybrid organic-inorganic materials as coatings for protecting wood
    Girardi, F.
    Cappelletto, E.
    Sandak, J.
    Bochicchio, G.
    Tessadri, B.
    Palanti, S.
    Feci, E.
    Di Maggio, R.
    PROGRESS IN ORGANIC COATINGS, 2014, 77 (02) : 449 - 457
  • [44] Structural control in germania hybrid organic-inorganic materials
    Alonso, B
    Massiot, D
    Babonneau, F
    Brusatin, G
    Della Giustina, G
    Kidchob, T
    Innocenzi, P
    CHEMISTRY OF MATERIALS, 2005, 17 (12) : 3172 - 3180
  • [45] Applications of hybrid organic-inorganic materials in chiral separation
    Wu, Qi
    Sun, Yaming
    Gao, Jie
    Dong, Shuqing
    Luo, Guoying
    Li, Hui
    Zhao, Liang
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2017, 95 : 140 - 148
  • [46] Investigation of organic-inorganic hybrid materials prepared by irradiation
    Falcao, AN
    Carrapiço, M
    Sousa, JS
    Margaça, FMA
    Ferreira, LM
    Carvalho, FG
    Salvado, IMM
    Teixeira, J
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) : 349 - 352
  • [47] Organic-inorganic hybrid perovskite materials and their application in transistors
    Liu, Yiran
    Liu, Yunqi
    Guo, Yunlong
    MATERIALS CHEMISTRY FRONTIERS, 2023, 7 (21) : 5215 - 5246
  • [48] Hybrid organic-inorganic materials - In search of synergic activity
    Gomez-Romero, P
    ADVANCED MATERIALS, 2001, 13 (03) : 163 - 174
  • [49] Solid freeform fabrication of organic-inorganic hybrid materials
    Calvert, P
    O'Kelly, J
    Souvignier, C
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 1998, 6 (2-3): : 167 - 174
  • [50] Advanced Organic-Inorganic Hybrid Materials for Optoelectronic Applications
    Zhou, Kun
    Qi, Bingyu
    Liu, Zhongwei
    Wang, Xinjiang
    Sun, Yuanhui
    Zhang, Lijun
    ADVANCED FUNCTIONAL MATERIALS, 2024,