Organic-inorganic hybrid materials doped with lithium ions

被引：0
|
作者：
Zelazowska, Elzbieta [1 ]
Borczuch-Laczka, Maria [2 ]
Rysiakiewicz-Pasek, Ewa [3 ]
机构：
[1] Inst Glass & Ceram, Cracow Branch, Ul Lipowa 3, PL-30702 Krakow, Poland
[2] AGH Univ Sci & Technol, Fac Mat Sci & Ceram, PL-30059 Krakow, Poland
[3] Wroclaw Univ Technol, Inst Phys, PL-50370 Wroclaw, Poland
来源：
OPTICA APPLICATA | 2008年 / 38卷 / 01期
关键词：
organic-inorganic hybrids; lithium-ion conductivity; sol-gel;
D O I：
暂无
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Organic-inorganic hybrid materials have been synthesized by the sol-gel method, using tetraethyl orthosilicate (TEOS), poly(ethylene oxide) (PEO), net-polyacrylic-inter-net-polysiloxane, butyl acrylate, ethyl acetoacetate, tetrahydrofuran, acetonitrile and LiClO4 precursors and additives. Mass fractions of the organic additions in the gels were of ca 35-40 mass%. The hybrid materials obtained were amorphous, colourless, transparent or translucent, with room temperature ionic conductivities in a range of 10(-4_)10(-3) Omega(-1)cm(-1). The results of scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM/EDX), Fourier transform infrared spectroscopy and Si-29 MAS Nuclear Magnetic Resonance analysis have revealed [SiO4] tetrahedrons polycondensation strongly influenced by organic precursors and chemical bonding between organic and inorganic parts of the gels obtained.
引用
收藏
页码：137 / 146
页数：10
相关论文
共 50 条
  • [21] Hybrid organic-inorganic materials for photonic applications
    Banerjee, Partha P.
    Evans, Dean R.
    Lee, Wei
    Reshetnyak, Victor Yu
    Tansu, Nelson
    OPTICAL MATERIALS EXPRESS, 2013, 3 (08): : 1149 - 1151
  • [22] CATALYSTS MADE OF ORGANIC-INORGANIC HYBRID MATERIALS
    SCHUBERT, U
    NEW JOURNAL OF CHEMISTRY, 1994, 18 (10) : 1049 - 1058
  • [23] Tuning the symmetry of hybrid organic-inorganic materials
    Mihalyi-Koch, Willa
    CHEM, 2024, 10 (07): : 1965 - 1967
  • [24] Hydrorepellent properties of organic-inorganic hybrid materials
    Cardiano, Paola
    Lo Schiavo, Sandra
    Piraino, Pasquale
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2010, 356 (18-19) : 917 - 926
  • [25] Monophasic organic-inorganic hybrid materials.
    Corriu, R
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1998, 1 (02): : 83 - 89
  • [26] Organic-inorganic planar hybrid materials for spasers
    Toropov, Nikita A.
    Kamalieva, Aisylu N.
    Vartanyan, Tigran A.
    NONLINEAR OPTICS AND APPLICATIONS IX, 2015, 9503
  • [27] Toughening of polycarbonate with organic-inorganic hybrid materials
    Zhang, ZY
    Zhao, N
    Wei, W
    Wu, D
    Sun, YH
    POLYMERS & POLYMER COMPOSITES, 2006, 14 (03): : 291 - 300
  • [28] Organic-inorganic hybrid materials processing and applications
    Schmidt, HK
    Mennig, M
    Nonninger, R
    Oliveira, PW
    Schirra, H
    ORGANIC/INORGANIC HYBRID MATERIALS II, 1999, 576 : 395 - 407
  • [29] Organic-Inorganic Hybrid Materials for Photonic Applications
    Shibata, Shuichi
    Yano, Tetsuji
    Segawa, Hiroyo
    IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2008, 14 (05) : 1361 - 1369
  • [30] Hybrid materials doped with lithium ions
    Zelazowska, Elzbieta
    Rysiakiewicz-Pasek, Ewa
    OPTICA APPLICATA, 2010, 40 (02) : 383 - 396
12345