Tris[(1,4,7,10,13,16-hexaoxacyclooctadecane)rubidium] heptaantimonide-ammonia (1/4)

被引：4

作者：

Mutzbauer, Fabian ^{[1
]}

Korber, Nikolaus ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

HOMOPOLYATOMIC ANIONS; CRYSTAL-STRUCTURE;

D O I：

10.1107/S1600536811041237

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, [Rb(C12H24O6)](3)-[Sb-7]center dot 4NH(3), fills the gap between the already known Zintl anion ammoniates {[Cs(18-crown-6)](3)Sb-7}(2)center dot 9NH(3) [Wiesler (2007). Dissertation, Universitat Regensburg, Germany] and [K(18-crown-6)](3)Sb-7 center dot 4NH(3) [Hanauer (2007). Dissertation, Universitat Regensburg, Germany]. As in the two known compounds, the antimony cage anion in this crystal structure is coordinated by three alkali cations. The coordination spheres of each of the cations are saturated by 18-crown-6 molecules. The ammonia molecules of crystallization are situated between the crown ethers. The neutral, molecular [Rb(18-crown-6)](3)Sb-7 units are interconnected by multiple dipole-dipole interactions between ammonia and 18-crown-6.

引用

页码：M1551 / +

页数：19

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