Tris[(1,4,7,10,13,16-hexaoxacyclooctadecane)rubidium] heptaantimonide-ammonia (1/4)

被引：4
|
作者：
Mutzbauer, Fabian [1 ]
Korber, Nikolaus [1 ]
机构：
[1] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
HOMOPOLYATOMIC ANIONS; CRYSTAL-STRUCTURE;
D O I：
10.1107/S1600536811041237
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [Rb(C12H24O6)](3)-[Sb-7]center dot 4NH(3), fills the gap between the already known Zintl anion ammoniates {[Cs(18-crown-6)](3)Sb-7}(2)center dot 9NH(3) [Wiesler (2007). Dissertation, Universitat Regensburg, Germany] and [K(18-crown-6)](3)Sb-7 center dot 4NH(3) [Hanauer (2007). Dissertation, Universitat Regensburg, Germany]. As in the two known compounds, the antimony cage anion in this crystal structure is coordinated by three alkali cations. The coordination spheres of each of the cations are saturated by 18-crown-6 molecules. The ammonia molecules of crystallization are situated between the crown ethers. The neutral, molecular [Rb(18-crown-6)](3)Sb-7 units are interconnected by multiple dipole-dipole interactions between ammonia and 18-crown-6.
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页码：M1551 / +
页数：19
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