Catalysts for methanol steam reforming-A review

被引:697
|
作者
Sa, Sandra [1 ]
Silva, Hugo [1 ]
Brandao, Lucia [1 ]
Sousa, Jose M. [1 ,2 ]
Mendes, Adelio [1 ]
机构
[1] Univ Porto, Fac Engn, LEPAE, Dept Engn Quim, P-4200465 Oporto, Portugal
[2] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001911 Vila Real Codex, Portugal
关键词
Catalysts; Hydrogen; Methanol steam reforming; SUPPORTED PD CATALYSTS; COPPER-BASED CATALYSTS; CU-BASED CATALYSTS; HYDROGEN-PRODUCTION; FUEL-CELL; MEMBRANE REACTOR; CU/ZNO/AL2O3; CATALYSTS; HOMOGENEOUS PRECIPITATION; PD/ZNO CATALYST; OXIDE CATALYSTS;
D O I
10.1016/j.apcatb.2010.06.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A large number of studies can be found in the literature regarding the production of new catalysts for methanol steam reforming. This work summarizes the latest developments on catalysts for this application and is divided in two main groups: copper-based and group 8-10 metal-based catalysts. In each section, the strategies proposed by several authors to enhance the performance of the catalysts are described. An overall comparison between the two groups shows that copper-based catalysts are the most active ones, while the 8-10 group catalysts present better results in terms of thermal stability and long-term stability. Very promising results were reported for both groups, enhancing the value of methanol as a hydrogen carrier for fuel cell applications. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:43 / 57
页数:15
相关论文
共 50 条
  • [41] Thermodynamics of the methanol steam reforming
    Lachowska, M
    INZYNIERIA CHEMICZNA I PROCESOWA, 2004, 25 (02): : 231 - 238
  • [42] Review on Hydrogen Production Reactor and System of Methanol Steam Reforming
    Li, Jiming
    Yang, Yang
    Zhu, Xun
    Ye, Dingding
    Chen, Rong
    Liao, Qiang
    Zhongguo Dianji Gongcheng Xuebao/Proceedings of the Chinese Society of Electrical Engineering, 2024, 44 (18): : 7276 - 7292
  • [43] Review of reaction kinetics of methanol steam reforming for hydrogen production
    Zhuang, Xiaoru
    Xu, Xinhai
    Xia, Xin
    Li, Lun
    Xu, Wenfu
    Huagong Jinzhan/Chemical Industry and Engineering Progress, 2020, 39 (01): : 152 - 165
  • [44] Application of microemulsion method for development of methanol steam reforming Pd/ZnO catalysts
    Pawlonka, Justyna
    Gac, Wojciech
    Greluk, Magdalena
    Slowik, Grzegorz
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 125 (03) : 1265 - 1272
  • [45] New Supported Pd and Pt Alloy Catalysts for Steam Reforming and Dehydrogenation of Methanol
    Nobuhiro Iwasa
    Nobutsune Takezawa
    Topics in Catalysis, 2003, 22 : 215 - 224
  • [46] Surface composition of materials used as catalysts for methanol steam reforming:: A theoretical study
    Lim, Kok Hwa
    Moskaleva, Lyudmila V.
    Roesch, Notker
    CHEMPHYSCHEM, 2006, 7 (08) : 1802 - 1812
  • [47] Steam reforming of methanol over copper-manganese spinel oxide catalysts
    Papavasiliou, J
    Avgouropoulos, G
    Ioannides, T
    CATALYSIS COMMUNICATIONS, 2005, 6 (07) : 497 - 501
  • [48] Supported Cu catalysts with yttria-doped ceria for steam reforming of methanol
    Cheng, WH
    Chen, IW
    Liou, JS
    Lin, SS
    TOPICS IN CATALYSIS, 2003, 22 (3-4) : 225 - 233
  • [49] New supported Pd and Pt alloy catalysts for steam reforming and dehydrogenation of methanol
    Iwasa, N
    Takezawa, N
    TOPICS IN CATALYSIS, 2003, 22 (3-4) : 215 - 224
  • [50] The role of urea in Cu-Zn-Al catalysts for methanol steam reforming
    Henpraserttae, Suparoek
    Limthongkul, Pimpa
    Toochinda, Pisanu
    MONATSHEFTE FUR CHEMIE, 2010, 141 (03): : 269 - 277