Catalysts for methanol steam reforming-A review

被引：697
|
作者：
Sa, Sandra [1 ]
Silva, Hugo [1 ]
Brandao, Lucia [1 ]
Sousa, Jose M. [1 ,2 ]
Mendes, Adelio [1 ]
机构：
[1] Univ Porto, Fac Engn, LEPAE, Dept Engn Quim, P-4200465 Oporto, Portugal
[2] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001911 Vila Real Codex, Portugal
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2010年 / 99卷 / 1-2期
关键词：
Catalysts; Hydrogen; Methanol steam reforming; SUPPORTED PD CATALYSTS; COPPER-BASED CATALYSTS; CU-BASED CATALYSTS; HYDROGEN-PRODUCTION; FUEL-CELL; MEMBRANE REACTOR; CU/ZNO/AL2O3; CATALYSTS; HOMOGENEOUS PRECIPITATION; PD/ZNO CATALYST; OXIDE CATALYSTS;
D O I：
10.1016/j.apcatb.2010.06.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A large number of studies can be found in the literature regarding the production of new catalysts for methanol steam reforming. This work summarizes the latest developments on catalysts for this application and is divided in two main groups: copper-based and group 8-10 metal-based catalysts. In each section, the strategies proposed by several authors to enhance the performance of the catalysts are described. An overall comparison between the two groups shows that copper-based catalysts are the most active ones, while the 8-10 group catalysts present better results in terms of thermal stability and long-term stability. Very promising results were reported for both groups, enhancing the value of methanol as a hydrogen carrier for fuel cell applications. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 57
页数：15
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