Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

被引：12
|
作者：
Braunschweig, Holger [1 ]
Friedrich, Maria [1 ]
Kupfer, Thomas [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期
关键词：
RING-OPENING POLYMERIZATION; TRANSITION-METAL; STRAINED METALLOCENOPHANES; ELECTRONIC-STRUCTURE; BRIDGE; REACTIVITY; NICKEL; ROUTE; ANSA;
D O I：
10.1039/c1cc10207a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[1]Zirconametalloarenophanes [Cr(eta(5)-C5H4)ZrCp'(2)(eta(7)-C7H6)] and [Mn(eta(5)-C5H4)ZrCp'2(eta(6)-C6H5)] (Cp' = (C5H4Bu)-Bu-t) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed by means of UV-visible spectroscopy and TD-DFT calculations.
引用
收藏
页码：3998 / 4000
页数：3
相关论文
共 50 条
  • [41] Metal removal from heavy metal-enriched plants by deep eutectic solvents and its mechanism investigation
    Zhang, Chenyuan
    Liu, Qiang
    He, Hailong
    Guo, Xinyu
    Yang, Shuang
    Zhang, Lei
    Wang, Lei
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 357
  • [42] Reduction of heavy metal contents in liquid effluents by vermicomposts and the use of the metal-enriched vermicomposts in lettuce cultivation
    Jordao, C. P.
    Fialho, L. L.
    Neves, J. C. L.
    Cecon, P. R.
    Mendonca, E. S.
    Fontes, R. L. F.
    BIORESOURCE TECHNOLOGY, 2007, 98 (15) : 2800 - 2813
  • [43] HEAVY-METAL UPTAKE BY PLEUROTUS-SAJOR-CAJU FROM METAL-ENRICHED DUCKWEED SUBSTRATE
    JAIN, SK
    GUJRAL, GS
    JHA, NK
    VASUDEVAN, P
    BIOLOGICAL WASTES, 1988, 24 (04): : 275 - 282
  • [44] Speciation and bioaccessibility of lead and cadmium in soil treated with metal-enriched Indian mustard leaves
    Yanshan Cui
    Journal of Environmental Sciences, 2011, (04) : 624 - 632
  • [45] Acute effects of metal-enriched soil samples upon immature blood cells and macrophages
    Chukhlovin, AB
    Yagunov, AS
    Tokalov, SV
    Reshchikov, AM
    Zharskaya, VD
    TRACE ELEMENTS AND ELECTROLYTES, 1996, 13 (03): : 151 - 154
  • [46] CAN SUPERMASSIVE BLACK HOLES FORM IN METAL-ENRICHED HIGH-REDSHIFT PROTOGALAXIES?
    Omukai, K.
    Schneider, R.
    Haiman, Z.
    ASTROPHYSICAL JOURNAL, 2008, 686 (02): : 801 - 814
  • [47] ELECTRONIC SPECTROSCOPIC STUDIES OF TRANSITION METAL-ENRICHED ZEOLITES .1. NICKEL-EXCHANGED ZEOLITE-L
    COUGHLAN, B
    MCCANN, WA
    CARROLL, WM
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1977, 62 (02) : 229 - 237
  • [48] Preferential magma extraction from K- and metal-enriched source regions in the crust
    Andrew G. Tomkins
    Roberto F. Weinberg
    Chris R. M. McFarlane
    Mineralium Deposita, 2009, 44 : 171 - 181
  • [49] Preferential magma extraction from K- and metal-enriched source regions in the crust
    Tomkins, Andrew G.
    Weinberg, Roberto F.
    McFarlane, Chris R. M.
    MINERALIUM DEPOSITA, 2009, 44 (02) : 171 - 181
  • [50] Supermassive star formation via super competitive accretion in slightly metal-enriched clouds
    Chon, Sunmyon
    Omukai, Kazuyuki
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2020, 494 (02) : 2851 - 2860
12345