Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

被引：12
|
作者：
Braunschweig, Holger [1 ]
Friedrich, Maria [1 ]
Kupfer, Thomas [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期
关键词：
RING-OPENING POLYMERIZATION; TRANSITION-METAL; STRAINED METALLOCENOPHANES; ELECTRONIC-STRUCTURE; BRIDGE; REACTIVITY; NICKEL; ROUTE; ANSA;
D O I：
10.1039/c1cc10207a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[1]Zirconametalloarenophanes [Cr(eta(5)-C5H4)ZrCp'(2)(eta(7)-C7H6)] and [Mn(eta(5)-C5H4)ZrCp'2(eta(6)-C6H5)] (Cp' = (C5H4Bu)-Bu-t) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed by means of UV-visible spectroscopy and TD-DFT calculations.
引用
收藏
页码：3998 / 4000
页数：3
相关论文
共 50 条
  • [21] The effects of binary stars on galaxies and metal-enriched gas during reionization
    Doughty, Caitlin
    Finlator, Kristian
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2021, 505 (02) : 2207 - 2223
  • [22] Comparison of metal enrichment in pyrite framboids from a metal-enriched and metal-poor estuary
    Gregory, Daniel
    Meffre, Sebastien
    Large, Ross
    AMERICAN MINERALOGIST, 2014, 99 (04) : 633 - 644
  • [23] Determination of Microelements in Sprouts Grown on Metal-Enriched Solutions by Ion Chromatography
    Blicharska, E.
    Komsta, L.
    Kocjan, R.
    Gumieniczek, A.
    Kloc, A.
    Kazmierczak, J.
    ACTA CHROMATOGRAPHICA, 2014, 26 (04) : 739 - 747
  • [24] Metal-enriched galactic outflows shape the mass-metallicity relationship
    Chisholm J.
    Tremonti C.
    Leitherer C.
    Chisholm, J. (john.chisholm@unige.ch), 1690, Oxford University Press (481) : 1690 - 1706
  • [25] Metal-enriched galactic outflows shape the mass-metallicity relationship
    Chisholm, J.
    Tremonti, C.
    Leitherer, C.
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2018, 481 (02) : 1690 - 1706
  • [26] The Geometry of Cold, Metal-enriched Gas around Galaxies at z ∼ 1.2
    Lundgren, Britt F.
    Creech, Samantha
    Brammer, Gabriel
    Kirse, Nathan
    Peek, Matthew
    Wake, David
    York, Donald G.
    Chisholm, John
    Erb, Dawn K.
    Kulkarni, Varsha P.
    Straka, Lorrie
    Tremonti, Christy
    van Dokkum, Pieter
    ASTROPHYSICAL JOURNAL, 2021, 913 (01):
  • [27] Hydrogen sulfide and metal-enriched atmosphere for a Jupiter-mass exoplanet
    Fu, Guangwei
    Welbanks, Luis
    Deming, Drake
    Inglis, Julie
    Zhang, Michael
    Lothringer, Joshua
    Ih, Jegug
    Moses, Julianne I.
    Schlawin, Everett
    Knutson, Heather A.
    Henry, Gregory
    Greene, Thomas
    Sing, David K.
    Savel, Arjun B.
    Kempton, Eliza M. -R.
    Louie, Dana R.
    Line, Michael
    Nixon, Matt
    NATURE, 2024, 632 (8026) : 752 - 756
  • [28] Metal-enriched galaxies in the first ∼1 billion years: evidence of a smooth metallicity evolution at z ∼ 5
    Poudel, Suraj
    Kulkarni, Varsha P.
    Cashman, Frances H.
    Frye, Brenda
    Peroux, Celine
    Rahmani, Hadi
    Quiret, Samuel
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2020, 491 (01) : 1008 - 1025
  • [29] Non-equilibrium cooling rate for a collisionally cooled metal-enriched gas
    Vasiliev, Evgenii O.
    MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, 2013, 431 (01) : 638 - 647
  • [30] Stress responses and metal tolerance of Chlamydomonas acidophila in metal-enriched lake water and artificial medium
    Spijkerman, Elly
    Barua, Deepak
    Gerloff-Elias, Antje
    Kern, Juergen
    Gaedke, Ursula
    Heckathorn, Scott A.
    EXTREMOPHILES, 2007, 11 (04) : 551 - 562
12345