Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers

被引：12
|
作者：
Braunschweig, Holger [1 ]
Friedrich, Maria [1 ]
Kupfer, Thomas [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 13期
关键词：
RING-OPENING POLYMERIZATION; TRANSITION-METAL; STRAINED METALLOCENOPHANES; ELECTRONIC-STRUCTURE; BRIDGE; REACTIVITY; NICKEL; ROUTE; ANSA;
D O I：
10.1039/c1cc10207a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[1]Zirconametalloarenophanes [Cr(eta(5)-C5H4)ZrCp'(2)(eta(7)-C7H6)] and [Mn(eta(5)-C5H4)ZrCp'2(eta(6)-C6H5)] (Cp' = (C5H4Bu)-Bu-t) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed by means of UV-visible spectroscopy and TD-DFT calculations.
引用
收藏
页码：3998 / 4000
页数：3
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