Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes

被引：10

作者：

Wang, Simin ^{[1
]}

Zhang, Qiao ^{[1
]}

Niu, Junbo ^{[1
]}

Guo, Xiaobing ^{[1
]}

Xiong, Tao ^{[1
]}

Zhang, Qian ^{[1
,2
]}

机构：

[1] Northeast Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 17期

关键词：

Allylic electrophile; Asymmetric hydroallylation; Chiral silane; CuH catalysis; Vinylsilane; SILICON-STEREOGENIC DIBENZOSILOLES; CARBON QUATERNARY STEREOCENTERS; ALLYLIC SUBSTITUTION-REACTIONS; H BOND INSERTION; ENANTIOSELECTIVE SYNTHESIS; C-H; RECENT PROGRESS; DEHYDROGENATIVE SILYLATION; ORGANOSILICON COMPOUNDS; ALKYLATION REACTIONS;

D O I：

10.1002/ejoc.202101575

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper-catalyzed asymmetric hydroallylation of readily available vinylsilanes with allylic phosphates in the presence of hydrosilane was developed. These transformations can be performed under mild reaction conditions and provide the useful chiral organosilanes with good to excellent level of enantiocontrol.

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页数：5

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